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- W2043670447 abstract "Lithium insertion is the fundamental electrochemical process of rechargeable lithium batteries. We report here in situ Raman and atomistic simulation studies of the lithium insertion process in β-AgVO3 nanowired structure material. Key issues of the process relate to structural variations and lithium migration pathways in the β-AgVO3. The simulation model shows good agreement with the experimental results. It indicates that the lithium insertion can be divided into three steps. The reduction sites at each step in the β-AgVO3 lattice are confirmed: the most favorable reduction sites at higher potential are V1/V4; at medium potential, Ag2/Ag3 are reduced and substituted; after that Li+ ion reduces V2/V3/Ag4 and further reduces V1/V4. The migration pathways of Li+ ions in β-AgVO3 are proposed for the first time. Our discovery would help us to greatly understand the deep insight of the Li+ insertion process in lithium batteries." @default.
- W2043670447 created "2016-06-24" @default.
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- W2043670447 date "2007-11-01" @default.
- W2043670447 modified "2023-10-18" @default.
- W2043670447 title "Lithium Insertion in Channel-Structured β-AgVO<sub>3</sub>: <i>In</i> <i>Situ</i> Raman Study and Computer Simulation" @default.
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- W2043670447 doi "https://doi.org/10.1021/cm071728i" @default.
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