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- W2043670462 abstract "Die Phase Pd8Sb3 hat die Raumgruppe R3c, die hexagonalen Gitterkonstanten a = 7.6152(7), c = 43.032(7) Å und einen Zellinhalt von 12 Formeleinheiten in der hexagonalen Zelle. Die Struktur ist eine Auffüllungs und Stapelvariante der Pd5Sb2-Struktur. Durch die Auffüllung der Zelle von Pd5Sb2 mit T-Atomen bei gleichbleibender Zahl von B-Atomen wird die Valenzelektronenkorrelation konserviert und damit der energetische Vorteil einer faktoriellen Kommensurabilität zwischen Valenz- und äusseren Rumpfelektronen. Die isotypen Phasen Pd20Zn7Te20, Pd73Ga6Te21, Pd73Ge7Te20, Pd73Sn10Te17, Pd72P6Te22, Pd73As6Te21und Pd73Bi17Te10 sind verträglich mit der Annahme über die Ortskorrelation der Valenzelektronen. Es werden auch die Bindungen in den übrigen analysierten kristallinen Phasen der Mischung Pd-Sb erörtert. The phase Pd8Sb3 has the space group R3c and the hexagonal lattice constants a = 7.6152(7) and c = 43.032(7) Å, with a cell content of 12 formula units in the hexagonal cell. The structure is a filling and stacking variant of the Pd5Sb2 structure. By feeding T atoms into the cell of Pd5Sb2 the valence electron correlation is conserved together with the energetic advantage of factorial commensurability between the valence electron and core electron correlations. The phases Pd20Zn7Te20, Pd73Ga6Te21, Pd73Ge7Te20, Pd73Sn10Te17, Pd72P6Te22, Pd73As6Te21 and Pd73Bi17Te10 have structures which are compatible with such an assumption regarding the spatial correlation of the valence electrons. The binding in the other analyzed crystalline phases of the Pd-Sb mixture discussed." @default.
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- W2043670462 date "1976-07-01" @default.
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- W2043670462 title "Kristallstruktur von pd8sb3" @default.
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