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• W2043747164 abstract "The addition of the CO32− dianion to the electrogenerated species Nb(η5-C5H3RR′)2Cl (2: R=H, R′ = SiMe3; 2′: R = R′ = SiMe3) gives in ca. 50% yields the anionic carbonato niobium(III) complex [Nb(η5-C5H3RR′)2(OC(O)O-O,O′)]− (3: R = H, R′ = SiMe3; 3′: R = R′ = SiMe3) which are oxidized electrochemically to the corresponding paramagnetic niobium(IV) complex [Nb(η5-C5H3RR′)2(OC(O)O-O,O′)] (5: R = R′ = SiMe3; 5′: R = R′ = SiMe3). These paramagnetic derivatives have been characterized by ESR and IR spectroscopy. Mechanistic aspects concerning the formation of 3 and 3′ are discussed. 3 can also be obtained from two-electron reduction of Nb(η5-C5H4SiMe3)2(O)Cl, 4, in the presence of carbon dioxide. The addition of the formate anion HCO2 to 3 gives the formato complex Nb(η5-C5H4SiMe3)2(OC(O)H-O,O′) 6." @default.
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• W2043747164 date "1996-11-01" @default.
• W2043747164 modified "2023-10-18" @default.
• W2043747164 title "Electrochemical synthesis and reactivity of carbonato-niobocene complexes" @default.
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• W2043747164 doi "https://doi.org/10.1016/s0022-328x(96)06507-2" @default.
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