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- W2043747391 abstract "Magnetic susceptibility measurements on the eclipsed layered structure series of $[mathrm{N}{mathrm{H}}_{3}{(mathrm{C}{mathrm{H}}_{2})}_{n}mathrm{N}{mathrm{H}}_{3}]mathrm{Cu}X$ ($n=2, 3, 4, mathrm{and} 5$ for $X={mathrm{Cl}}_{4}$ and $n=2$ for $X={mathrm{Cl}}_{2}{mathrm{Br}}_{2}$) indicate that the interplanar superexchange interaction along the linear Cu-Cl-Cl-Cu path has a significantly stronger Cu-Cu distance dependence than that for the typical $Mensuremath{-}Xensuremath{-}M$ ($M=mathrm{C}mathrm{u},phantom{rule{0ex}{0ex}}mathrm{M}mathrm{n},phantom{rule{0ex}{0ex}}mathrm{N}mathrm{i},phantom{rule{0ex}{0ex}}mathrm{C}mathrm{o}$; $X=mathrm{F},phantom{rule{0ex}{0ex}}mathrm{C}mathrm{l}$) path, and a stronger power-law metal-metal distance dependence than previously expected for the two-halide bridge case. Furthermore, the evidence indicates a 10th-power dependence on the halide-halide separation, which appears to be the critical parameter for determining the strength of the two-halide superexchange. Previously unpublished data on the partially bromated compound is included. The results of a Rayleigh-Schrodinger perturbation calculation of the two-halide superexchange strength are presented and the calculated results are compared with experimental values." @default.
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- W2043747391 title "Measurement and calculation of the superexchange interaction through the two-halide bridge in the eclipsed layered compounds<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mo>[</mml:mo><mml:mi mathvariant=normal>N</mml:mi><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>H</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msub></mml:mrow><mml:mrow><mml:msub><mml:mrow><mml:mo>(</mml:mo><mml:mi mathvariant=normal>C</mml:mi><mml:mrow><mml:…" @default.
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- W2043747391 doi "https://doi.org/10.1103/physrevb.24.5349" @default.
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