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- W2043759501 abstract "Activation of pure stoichiometric FeTi turned out to be difficult and deactivation processes due to gas impurities limit the hydrogen storage capability. Isotherms of deuterium desorption are reported for the temperature range T = (25÷70)°C. At room temperature the crystal structures of FeTiDx (x = 0÷1.74) and FeTiH0.78D0.22 were investigated by means of neutron diffraction at D2-pressures up to 84 bar. Deuterium absorption in FeTi yields ternary deuterides and is associated with symmetry reduction corresponding to considerable distortions of the CsCl-type metal structure. In FeTiD deuterium occupies octahedral sites with two iron and four titanium atoms as nearest neighbour coordination (space group P2221 or P2c). Hydrogenation does not change essentially the order parameter of FeTi." @default.
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- W2043759501 date "1978-09-01" @default.
- W2043759501 modified "2023-10-16" @default.
- W2043759501 title "Deuterium storage in FeTi. Measurement of desorption isotherms and structural studies by means of neutron diffraction" @default.
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- W2043759501 doi "https://doi.org/10.1016/0025-5408(78)90105-8" @default.
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