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- W2043759931 abstract "The reaction of 2-nitro-2-(4-pyridyl) propane (I) with lithium 2-propanenitronate, lithium cyclohexanenitronate, and sodium thiophenoxide affords excellent yields of the C-alkylation products 2-nitro-3-(4-pyridyl)-2,3-dimethylbutane (II), 2-(4-pyridyl)-2-(1-nitrocyclohexyl) propane (V) and 2-thiophenyl-2-(4-pyridyl) propane (VI), respectively. In contrast, the reaction of compound I with sodium azide does not afford the expected tertiary azide; but instead gives the dimer 2,3-bis(4-pyridyl)-2,3-dimethylbutane (III), in near quantitative yield. Evidence has been obtained that all of these transformations proceed via electron transfer pathways." @default.
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- W2043759931 date "1978-12-01" @default.
- W2043759931 modified "2023-09-24" @default.
- W2043759931 title "Reactions of 2-nitro-2-(4-pyridyl) propane with nucleophiles. Substitution at tertiary carbon" @default.
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- W2043759931 doi "https://doi.org/10.1002/jhet.5570150835" @default.
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