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- W2043804583 abstract "The pseudobinary systems ACl/LaCl3 (A ≡ Na — Cs) were reinvestigated by means of DTA. The following compounds were found and identified by their X-ray patterns (primarily detected compounds are underlined): NaLa1.67Cl6; K2LaCl5, KLa1.67Cl6; Rb3LaCl6, Rb2LaCl5, RbLa2Cl7; Cs3LaCl6, Cs2LaCl5, CsLa2Cl7. The compounds A2LaCl5 crystallize with the K2PrCl5 structure. The high-temperature modifications of the compounds A3MCl6 have the cubic elpasolite structure; the hexagonal unit cell of KLa1.67Cl6 is related to the LaCl3 structure: 0.33La3+ are substituted by one K+. The thermodynamic functions for the reactions nACl + LaCl3 = AnLaCln + 3 were determined by e.m.f. measurements in a galvanic cell for solid electrolytes. Measurements of the e.m.f.'s E yielded the Gibbs enthalpies ΔGr, using the relation ΔGr = −nFE. From the temperature dependence of E, ΔSr and ΔHr were also obtained. Additionally, ΔHr298 was measured by solution calorimetry. The most important result is that the formation of the elpasolites according to the equation ACl + A2LaCl5 = A3LaCl6 is associated with a loss of lattice enthalpy compensated by a high gain in entropy." @default.
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- W2043804583 date "1985-08-01" @default.
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- W2043804583 title "Thermodynamic properties of double chlorides in the systems ACl/LaCl3 (A ≡ Na, K, Rb, Cs)" @default.
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- W2043804583 doi "https://doi.org/10.1016/0022-5088(85)90315-7" @default.
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