Matches in SemOpenAlex for { <https://semopenalex.org/work/W2043817847> ?p ?o ?g. }
Showing items 1 to 87 of
87
with 100 items per page.
- W2043817847 endingPage "703" @default.
- W2043817847 startingPage "699" @default.
- W2043817847 abstract "The composition and structure of a preparation of 'cord factor' (di-beta-hydroxy acyl trehaloses) from Corynebacterium diphtheriae have been determined by a combination mass spectral ionization methods. The methods were tested by means of synthetic 6,6'-dicorynomycolate of alpha-D-trehalose prior to their use on natural products. The determination of the molecular weight of the components and the estimation of their relative abundance in the natural mixture were made by field desorption mass spectrometry and cationization by means of cesium iodide. At least 22 molecular species differing from the chain length and the unsaturation degree were detected (carbon numbers C76 to C66). The position of acylation and the nature of the acyl chains were obtained from the electron impact mass spectra of the trimethylsilyl derivatives. The trehalose molecular was found to be esterified by a complex mixture of corynomycolic acids (3-hydroxy 2-alkyl fatty acids) which were present as saturated, mono-unsaturated and di-unsaturated homologues (carbon numbers C32 to C24). The 6 and 6' sites of acylation were the only detectable ones." @default.
- W2043817847 created "2016-06-24" @default.
- W2043817847 creator A5032734109 @default.
- W2043817847 creator A5073547885 @default.
- W2043817847 creator A5078317170 @default.
- W2043817847 creator A5083433720 @default.
- W2043817847 creator A5088209315 @default.
- W2043817847 date "1978-12-01" @default.
- W2043817847 modified "2023-10-09" @default.
- W2043817847 title "Structural determination of ‘cord factor’ from aCorynebacterium diphtheriae strain by a combination of mass spectral ionization methods: Field desorption cesium cationization and electron impact mass spectrometry studies" @default.
- W2043817847 cites W1835258770 @default.
- W2043817847 cites W1856085303 @default.
- W2043817847 cites W1905500612 @default.
- W2043817847 cites W1932712619 @default.
- W2043817847 cites W1941320029 @default.
- W2043817847 cites W1967947821 @default.
- W2043817847 cites W1985185565 @default.
- W2043817847 cites W2014553953 @default.
- W2043817847 cites W2026703104 @default.
- W2043817847 cites W2035867146 @default.
- W2043817847 cites W2061201473 @default.
- W2043817847 cites W2075099807 @default.
- W2043817847 cites W2080583647 @default.
- W2043817847 cites W2097931555 @default.
- W2043817847 cites W4243779121 @default.
- W2043817847 doi "https://doi.org/10.1002/bms.1200051212" @default.
- W2043817847 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/106902" @default.
- W2043817847 hasPublicationYear "1978" @default.
- W2043817847 type Work @default.
- W2043817847 sameAs 2043817847 @default.
- W2043817847 citedByCount "15" @default.
- W2043817847 countsByYear W20438178472014 @default.
- W2043817847 countsByYear W20438178472015 @default.
- W2043817847 crossrefType "journal-article" @default.
- W2043817847 hasAuthorship W2043817847A5032734109 @default.
- W2043817847 hasAuthorship W2043817847A5073547885 @default.
- W2043817847 hasAuthorship W2043817847A5078317170 @default.
- W2043817847 hasAuthorship W2043817847A5083433720 @default.
- W2043817847 hasAuthorship W2043817847A5088209315 @default.
- W2043817847 hasConcept C113196181 @default.
- W2043817847 hasConcept C145148216 @default.
- W2043817847 hasConcept C161790260 @default.
- W2043817847 hasConcept C162356407 @default.
- W2043817847 hasConcept C178790620 @default.
- W2043817847 hasConcept C185592680 @default.
- W2043817847 hasConcept C193557335 @default.
- W2043817847 hasConcept C198291218 @default.
- W2043817847 hasConcept C201268389 @default.
- W2043817847 hasConcept C205759337 @default.
- W2043817847 hasConcept C38438003 @default.
- W2043817847 hasConcept C40325409 @default.
- W2043817847 hasConcept C43617362 @default.
- W2043817847 hasConceptScore W2043817847C113196181 @default.
- W2043817847 hasConceptScore W2043817847C145148216 @default.
- W2043817847 hasConceptScore W2043817847C161790260 @default.
- W2043817847 hasConceptScore W2043817847C162356407 @default.
- W2043817847 hasConceptScore W2043817847C178790620 @default.
- W2043817847 hasConceptScore W2043817847C185592680 @default.
- W2043817847 hasConceptScore W2043817847C193557335 @default.
- W2043817847 hasConceptScore W2043817847C198291218 @default.
- W2043817847 hasConceptScore W2043817847C201268389 @default.
- W2043817847 hasConceptScore W2043817847C205759337 @default.
- W2043817847 hasConceptScore W2043817847C38438003 @default.
- W2043817847 hasConceptScore W2043817847C40325409 @default.
- W2043817847 hasConceptScore W2043817847C43617362 @default.
- W2043817847 hasIssue "12" @default.
- W2043817847 hasLocation W20438178471 @default.
- W2043817847 hasLocation W20438178472 @default.
- W2043817847 hasOpenAccess W2043817847 @default.
- W2043817847 hasPrimaryLocation W20438178471 @default.
- W2043817847 hasRelatedWork W1976221070 @default.
- W2043817847 hasRelatedWork W1980296382 @default.
- W2043817847 hasRelatedWork W2028288201 @default.
- W2043817847 hasRelatedWork W2031957996 @default.
- W2043817847 hasRelatedWork W2052338166 @default.
- W2043817847 hasRelatedWork W2072559060 @default.
- W2043817847 hasRelatedWork W2092749942 @default.
- W2043817847 hasRelatedWork W2192602537 @default.
- W2043817847 hasRelatedWork W2520164007 @default.
- W2043817847 hasRelatedWork W2106194216 @default.
- W2043817847 hasVolume "5" @default.
- W2043817847 isParatext "false" @default.
- W2043817847 isRetracted "false" @default.
- W2043817847 magId "2043817847" @default.
- W2043817847 workType "article" @default.