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- W2043837697 abstract "An inherently disorganized self-assembled monolayer (SAM) of 2-mercapto-3-n-octylthiophene (MOT) has been formed on a gold bead electrode from its dilute ethanolic solution. The disorganization of the monolayer is attributed to the loose packing of the aliphatic chains of the MOT adsorbates, which results from a large difference in dimension/or cross-sectional area between the head (thiophene thiolate) and the tail (alkane chain) groups. Electrochemical measurements including ac impedance spectroscopy and metal underpotential deposition have shown that the monolayer is almost pinhole free. However, the MOT SAM can be penetrated by an organic probe molecule with affinity for the alkane chain part of the monolayer. Some typical probe molecules with different size and hydrophilicity have been employed to assess the permselectivity of the monolayer. Measurement results demonstrate that the ability of the employed probe molecules to penetrate into the monoalyer is mainly dominated by their hydrophilicity/or hydrophobicity. The results presented here suggest the potential application of MOT monoalyer to effectively modify the electrode surface for several research areas such as electrochemical sensors, electrocatalysis, electroanalysis, and supported hybrid bilayer membranes. © 2003 The Electrochemical Society. All rights reserved." @default.
- W2043837697 created "2016-06-24" @default.
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- W2043837697 date "2003-01-01" @default.
- W2043837697 modified "2023-09-23" @default.
- W2043837697 title "Selective Penetration of Liquid-Phase Organic Probe Molecules into SAM of 2-Mercapto-3-n-octylthiophene" @default.
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- W2043837697 doi "https://doi.org/10.1149/1.1554726" @default.
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