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- W2043856618 abstract "Salt metathesis has been exploited in the synthesis of M–Al bonds, stabilized by a variety of chelating N-donor substituents at aluminium and including the first examples of such systems featuring ancillary guanidinato frameworks. Importantly, this synthetic approach can be extended to the synthesis of σ-alane complexes through the use of hydride-containing transition metal nucleophiles. Cp′Mn(CO)2-[H(Cl)Al{(NiPr)2CPh}] synthesized via this route features an alane ligand bound in a more ‘side-on’ fashion than other alane complexes, although DFT calculations imply that the potential energy surface associated with variation in the Mn–H–Al angle is a very soft one." @default.
- W2043856618 created "2016-06-24" @default.
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- W2043856618 date "2013-01-01" @default.
- W2043856618 modified "2023-10-07" @default.
- W2043856618 title "Salt metathesis for the synthesis of M–Al and M–H–Al bonds" @default.
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- W2043856618 doi "https://doi.org/10.1039/c2dt31974h" @default.
- W2043856618 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23069776" @default.
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