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• W2043916135 abstract "The optical spectrum of matrix-isolated silver dimers has been obtained in the photon energy region from 2 to 10 eV by combined absorption and emission yield spectroscopy utilizing synchrotron radiation. With the help of emission yield studies the dimer spectrum was discriminated against that of the atom and of higher clusters, both of which are always present to some extent in the matrix. Besides the well-known absorption lines of Ag2 in the 3 to 5 eV range, we observed a second group of bands around 7 to 8 eV, which is assigned to transitions from the 4d-derived levels in the silver dimer. From this, the bary center of the 4d-derived states is inferred to lie in energy about 4.5 eV below the 5s-derived Σg ground state." @default.
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• W2043916135 date "1985-06-01" @default.
• W2043916135 modified "2023-09-26" @default.
• W2043916135 title "The optical spectrum of matrix-isolated Ag2" @default.
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• W2043916135 doi "https://doi.org/10.1016/0039-6028(85)90249-3" @default.
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