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- W2043917948 abstract "Abstract Two step synthesis of educts for the synthesis of poly( p -xylylene)s was accomplished by Grignard-type coupling reaction of 4-bromotoluene and different aldehydes or p -tolylaldehyde and different aryl bromides followed by conversion of alcohols into corresponding chlorides. Derivatives of poly( p -xylylene) (PPX) were obtained by vapor phase pyrolysis/chemical vapor deposition (CVD) or Gilch-type polymerization of these chlorides. Functional groups along the PPX main chain were introduced by substituted phenyl rings in a-position. The resulting PPXs are soluble under ambient conditions and are amorphous in the solid state. The glass transition temperatures varied only slightly with substituents on the phenyl ring in a-position. Significant enhancement by substituents was found for the thermal stability under nitrogen and a considerable decrease of the surface energies by fluorinated substituents." @default.
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- W2043917948 date "2001-12-01" @default.
- W2043917948 modified "2023-10-17" @default.
- W2043917948 title "Synthesis and structure-property relationships of novel poly(p-xylylene)s with aromatic substituents" @default.
- W2043917948 doi "https://doi.org/10.1515/epoly.2001.1.1.25" @default.
- W2043917948 hasPublicationYear "2001" @default.
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