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- W2043919745 abstract "Tetrathiooxalsäure-dimethylester (1) bildet mit allen untersuchten Diazoverbindungen 2 in einheitlicher Reaktion die 1,3-Dithiole 3. Komplexe Produktgemische entstehen hingegen bei der Umsetzung von Dithiooxalsäure-O, O-dimethylester (6) mit Diazoverbindungen. Näher untersucht wurde die Reaktion von 6 mit Diazomethan, Diazoethan, 2-Diazopropan und Diphenyl-diazomethan. Thiono and Dithio Esters, XXIX. Reactions of Diazo Compounds with Thiooxalates Dimethyl tetrathiooxalate (1) reacts with all diazo compounds 2 investigated to form 1,3-dithioles 3 in high yield. Complex mixtures of products, however, are obtained from O,O-dimethyl dithiooxalate (6) and diazo compounds. The reactions of 6 with diazomethane, diazoethane, 2-diazopropane and diphenyldiazomethane were investigated more in detail." @default.
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- W2043919745 date "1982-09-01" @default.
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- W2043919745 title "Thion‐ und Dithioester, XXIX. Reaktionen von Diazoverbindungen mit Thiooxalestern" @default.
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- W2043919745 doi "https://doi.org/10.1002/cber.19821150915" @default.
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