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- W2043922443 abstract "Abstract Brittle single-crystals of CaAu2 and SrAu2 were synthesized by the reaction of alkaline earth metals and gold powder at 750°C. The structures were determined from X-ray single-crystal diffractometer data. CaAu2: Imma, Z = 4, a = 4.611(1) A , b = 7.067(2) A , c = 8.079(2) A , R/R w (w = 1) = 0.069/0.071 for 248 structure factors with Fo2 ⩾ 3σ(Fo2) and 11 variables. SrAu2: Imma, Z = 4, a = 4.732(2) A , b = 7.484(2) A , c = 8.165(3) A , R/R w (w = 1) = 0.032/0.038 for 542 structure factors with Fo2 ⩾ 3σ(Fo2) and 12 variables. Both compounds crystallize with the KHg2 (CeCu2) structure type. The structures consist of three-dimensional gold frameworks with a trigonal pyramidal 3 + 1 coordination for each gold atom. Calcium and strontium occupy channel-like cavities within the gold partial structures." @default.
- W2043922443 created "2016-06-24" @default.
- W2043922443 creator A5002000632 @default.
- W2043922443 date "2010-08-05" @default.
- W2043922443 modified "2023-09-25" @default.
- W2043922443 title "ChemInform Abstract: Synthesis and Structure of CaAu2 and SrAu2." @default.
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- W2043922443 doi "https://doi.org/10.1002/chin.199630006" @default.
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