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• W2043925049 abstract "It has been shown that carbon dioxide reacts with acetylene complexes of titanocene Cp2Ti(RC2R) (RPh, SiMe3) at room temperature and atmospheric pressure to form binuclear σ-alkenylcarboxylate complexes of trivalent titanium Cp2TiC(R)C(R)COOTiCp2 containing two fused chelate cycles and a tricoordinated oxygen atom. The interaction of these binuclear carboxylate complexes with air oxygen at 20°C results in rapid formation of titanafuranone metallacycles Cp2 Ti(R)=C(R)C(O)O. X-ray diffraction studies of complexes Cp2TiC(SiMe3)C(SiMe3)COOTiCp2 and Cp2 Ti(Ph)=C(Ph)C(O)O have been carried out." @default.
• W2043925049 created "2016-06-24" @default.
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• W2043925049 date "1997-09-01" @default.
• W2043925049 modified "2023-09-27" @default.
• W2043925049 title "Interaction of carbon dioxide with acetylene complexes of titanocene Cp2Ti(RC2R) (R Ph, SiMe3). Synthesis and structure of binuclear σ-alkenylcarboxylate complexes of titanium (III) Cp2TiC(R)C(R) COOTiCp2 and unexpected transformation of these complexes into titanafuranone metallacycles under the action of air oxygen" @default.
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• W2043925049 doi "https://doi.org/10.1016/s0022-328x(97)00288-x" @default.
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