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• W2043926504 abstract "We study the kinetics of the isotropic-smectic phase transition in a colloidal rod/polymer mixture by visualizing individual smectic layers. First, we show that the bulk isotropic-smectic phase transition is preceded by a surface freezing transition in which a quasi-two-dimensional smectic phase wets the isotropic-nematic interface. Next, we identify a two-step kinetic pathway for the formation of a bulk smectic phase. In the first step a metastable isotropic-nematic interface is formed. This interface is wetted by the surface-induced smectic phase. In the subsequent step, smectic layers nucleate at this surface phase and grow into the isotropic bulk phase." @default.
• W2043926504 created "2016-06-24" @default.
• W2043926504 creator A5001208796 @default.
• W2043926504 date "2003-10-16" @default.
• W2043926504 modified "2023-09-27" @default.
• W2043926504 title "Surface Freezing and a Two-Step Pathway of the Isotropic-Smectic Phase Transition in Colloidal Rods" @default.
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• W2043926504 doi "https://doi.org/10.1103/physrevlett.91.165701" @default.
• W2043926504 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/14611416" @default.
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