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- W2043946319 abstract "Die Redoxeigenschaften sieben dreikerniger Cluster mit zwei dreifach verbrückenden Liganden der allgemeinen Formel (LnM)3 E2 (1a–g) wurden elektrochemisch bestimmt. Oxidationsstufen, die sich um bis zu sechs Ladungen unterscheiden, waren erreichbar, und bis zu vier Oxidationsstufen waren stabil. Die Zugänglichkeit und Reversibilität der Redox-Schritte hängt von der Art der Liganden und der Zahl vorhandener Valenzelektronen ab. Redox Chemistry of Ligand Bridged Trinuclear Clusters The redox properties of seven trinuclear clusters with two triply bridging ligands of the general formula (LnM)3 E2(1a–g) were determined electrochemically. Oxidation states differing by up to six units were accessible, and up to four oxidations states were stable. The possibility and reversibility of the redox steps depend on he types of ligands and on the number of valence electrons present." @default.
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- W2043946319 date "1981-02-01" @default.
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- W2043946319 title "Redox‐Chemie ligandverbrückter Dreikerncluster" @default.
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- W2043946319 doi "https://doi.org/10.1002/cber.19811140212" @default.
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