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- W2043983883 abstract "The reaction of trans-[Cr(Salen)(OH2)2]+ with aqueous sulfite yields trans-[Cr(Salen)(OH2)(OSO2(SINGLEBOND)O)]− (O-bonded isomer). The rate and activation parameter data for the formation of the sulfito complex are consistent with a mechanism involving rate-limiting addition of SO2 to the CrIII(SINGLEBOND)OH bond. The complex ions, trans-[(OH2)Cr(Salen)(OSO2(SINGLEBOND)O)]−, and trans-[(OH)Cr(Salen)(OSO2(SINGLEBOND)O)]2−, undergo reversible anation by NCS−, N3−, imidazole, and pyridine resulting in the formation of trans-[XCr(Salen)(OSO2(SINGLEBOND)O)](N+1)−(n=1 for X=N3−,NCS−, and 0 for X=imidazole and pyridine) predominantly via dissociative interchange mechanism. The labilizing action of the coordinated sulfite on the trans-CrIII-X bond in trans-[XCr(Salen)(OSO2)](n+1)− follows the sequence: NCS−pyridine ca. N3− ca. imidazole. Data analysis indicated that the coordinated sulfite has little trans activating influence. © 1998 John Wiley & Sons, Inc. Int J Chem Kinet 30: 373–384, 1998" @default.
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- W2043983883 date "1998-01-01" @default.
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- W2043983883 title "Kinetics and mechanism of reaction oftrans-(diaqua)(N,N?-ethylene-bis-salicylidenimine) chromium(iii) with sulfur(iv): The labilizing effect of coordinated sulfite" @default.
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- W2043983883 doi "https://doi.org/10.1002/(sici)1097-4601(1998)30:5<373::aid-kin8>3.0.co;2-p" @default.
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