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- W2043995737 abstract "Acid chlorides and aromatic aldehydes react in the presence of a stoichiometric amount of a tertiary amine and catalytic amounts of a cinchona alkaloid derivative and a Lewis acid to produce β-lactones in high diastereo- and enantioselectivity. The sense of the diastereoselectivity depends on the substitution of the acid chloride, with the reactions of aliphatic acid chlorides giving predominantly the trans-isomer and those of alkoxyacetyl chlorides favoring formation of the cis-isomer." @default.
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- W2043995737 date "2005-03-26" @default.
- W2043995737 modified "2023-10-15" @default.
- W2043995737 title "Formation of Disubstituted β-Lactones Using Bifunctional Catalysis" @default.
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- W2043995737 doi "https://doi.org/10.1021/ol050411q" @default.
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