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- W2044009065 abstract "Treatment of the nickel(II)-substituted zeolite A with 1, 2-diaminoethane ( en ), 1, 2-diaminopropane ( pnd ), and 1, 3-diaminopropane ( tmd ) yields products (NiA- en , NiA- pnd , and Nia- tmd , respectively) distinguished by the presence of two kinds of Ni 2+ coordination sites. One site contains the Ni 2+ ion octahedrally coordinated only by O-atom donors. The other site has, for NiA- en and NiA- pnd , the octahedral environment around Ni 2+ , the ion being bound to one diamine ligand; for NiA- tmd , there is a square planar Ni( tmd ) 2 2+ complex. A fraction of the diamine content is, in all cases, present in the system in cationic form." @default.
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- W2044009065 date "1988-05-01" @default.
- W2044009065 modified "2023-09-27" @default.
- W2044009065 title "Cation sites and ligand exchange on nickel(II) zeolite A" @default.
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- W2044009065 doi "https://doi.org/10.1016/s0144-2449(88)80314-2" @default.
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