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- W2044017105 abstract "A simple and reproducible method is presented for preparing b-oriented MFI films on plane (disc) and curved (hollow fiber) supports by in situ hydrothermal synthesis. A mesoporous silica (sub-)layer was pre-coated on the supports by dip coating followed by a rapid thermal calcination step (973 K during 1 min) to reduce the number of grain boundaries while keeping the hydrophilic behavior of silica. The role of the silica sub-layer is not only to smoothen the substrate surface, but also to provide a silica source to promote the nucleation and growth of zeolite crystals via a heterogeneous nucleation mechanism (zeolitization), and adsorb zeolite moieties generated in the synthesis solution via a homogeneous nucleation mechanism. A monolayer of b-oriented MFI crystals was obtained on both supports after 3 h synthesis time with a moderate degree of twinning on the surface." @default.
- W2044017105 created "2016-06-24" @default.
- W2044017105 creator A5010609915 @default.
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- W2044017105 date "2013-05-01" @default.
- W2044017105 modified "2023-10-03" @default.
- W2044017105 title "In situ crystallization of b-oriented MFI films on plane and curved substrates coated with a mesoporous silica layer" @default.
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- W2044017105 doi "https://doi.org/10.1016/j.materresbull.2013.01.020" @default.
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