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- W2044018943 abstract "Abstract Attempted syntheses of ruthenium(II) monosubstituted squarate complexes in acetonitrile using cis-[RuCl2(dmso)4] and anisole-, methoxy-, methyl- and diphenylamino-squarate ligands, respectively, resulted in the formation in each case of the monomer cis, fac-Ru(CH3CN)Cl2(dmso)3 (1) with the ruthenium atom in a distorted octahedral environment. A second crop of crystals harvested from the reaction with the methoxysquarate ligand was identified as the oxalato-bridged dimer [{cis-(CH3CN)(Cl)(dmso)2Ru}2(μ-C2O4)] (2). When cis-[RuCl2(dmso)4] and methylsquarate were reacted in aqueous solution instead of acetonitrile, the dimer [{fac-(Cl)(dmso)3Ru}2(μ-C2O4)] (3) was produced. The dimers 2 and 3 are formed from oxidation/ring opening of the methoxy- and methyl-squarate ligands, respectively. Use of the salts of these ligands instead of their non-ionised forms under different reaction conditions, afforded [Na] fac-[RuCl3(dmso)3] (4) and [(C4H9)4N]2[(C4O4)(C4H2O4)2] (7), respectively, which were shown to be products of competing reactions. The information acquired from these failed attempts has provided the basis for the development of a strategy to overcome these problems and lead to a successful synthetic route to ruthenium(II) monosubstituted squarates." @default.
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- W2044018943 date "2004-01-01" @default.
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- W2044018943 title "Synthesis of ruthenium(II) monosubstituted squarates: 1. Procedural considerations" @default.
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- W2044018943 doi "https://doi.org/10.1016/s0020-1693(03)00424-9" @default.
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