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- W2044097296 abstract "We have recently published a kinetic mathematical model, based upon multiple active site distribution approach, for olefins polymerized with heterogeneous Ziegler-Natta catalysts1. Thismodel can be used to calculate not only production rates, but also both broad molecular weight and copolymer composition (temperature rising elution fractionation (TREF)) distributions. We now extend this model to account for both the stereo and the chemical sequence length distributions. We focus our analysis on α-olefin homopolymers and α-olefin-ethylene copolymers. The α-olefin must not be polymerizable by another mechanism (ionic or radical), so that styrene is not considered. Some simulations are carried out for typical productions of polypropylene and propylene-ethylene copolymer." @default.
- W2044097296 created "2016-06-24" @default.
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- W2044097296 date "1990-07-01" @default.
- W2044097296 modified "2023-10-15" @default.
- W2044097296 title "A kinetic model for heterogeneous Ziegler-Natta (co)polymerization. Part 2: stereochemical sequence length distributions" @default.
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- W2044097296 doi "https://doi.org/10.1016/0032-3861(90)90222-k" @default.
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