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- W2044101515 abstract "Solutions of sodium dinonyl naphthalene sulphonate and sodium hydrogen dinonyl naphthalene sulphonate in nonpolar organic liquids are shown to serve as analogues of cross-linked resinous cation-exchangers. For cobalt (II)-glycolate and cobalt (II)-citrate systems, the formation constants of the 1:1 complexes agree well with the values obtained by resinous cation-exchange method. Moreover, the liquid exchanger enables the formation constant of the 1:2 complex to be obtained whereas the resinous cation-exchange method fails. Nuclear magnetic resonance studies of the organic phase for cobalt-imidazole and indium-acetate systems demonstrate that CoIm2+ and InAc2+ complexes, with charge of 2+, are extracted into the organic phase. The 1:1 zinc-acetate complex, with a charge of 1+ only, is not extracted. A postulated equation for the extraction of divalent metal ion by sodium dinonyl naphthalene sulphonate, which is polymeric and is designated (NaD)χ is: M2+A+ (NaD)χo = M(Naχ−2Dχ)o + 2Na+A where the subscripts A and O denote the aqueuos and organic phases, respectively." @default.
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- W2044101515 date "1965-09-01" @default.
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- W2044101515 title "Sodium dinonyl naphthalene sulphonate as liquid ion-exchanger" @default.
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- W2044101515 doi "https://doi.org/10.1016/0022-1902(65)80065-3" @default.
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