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- W2044111954 abstract "Abstract The mechanism of extraction of plutonium (IV) in tri- n -butyl phosphate (TBP), methyl isobutyl ketone (hexone) and di-ethylene glycol di-butyl ether (butex) has been studied by the method of two phase equilibria varying the concentrations of nitrate and hydrogen ion in the aqueous phase. The results show that plutonium (IV) is associated with an average of 2·6 nitrate ions in aqueous phase over a concentration range of 2–4 M nitrate ions. Furthermore plutonium (IV) in and upto 6·7 M nitrate concentration is extracted as Pu(NO 3 ) 4 in hexone and butex and thereafter adds on HNO 3 in the organic phase to form H 2 Pu(NO 3 ) 6 . This is supported by the evidence obtained by studying the absorption spectra of solutions both in the aqueous and organic phases." @default.
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- W2044111954 date "1964-07-01" @default.
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- W2044111954 title "Mechanism of extraction of plutonium (IV) in organic solvents" @default.
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- W2044111954 doi "https://doi.org/10.1016/0022-1902(64)80214-1" @default.
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