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- W2044128456 abstract "A new method for building aryl aryl ketones containing heterocyclic rings through chelation-assisted C–O bond activation catalyzed by a rhodium complex has been developed. In this reaction, methyl quinoline-8-carboxylate, methyl quinoxaline-5-carboxylate, and their derivatives were reacted with an excess amount of a substituted phenyl boronic acid in the presence of a rhodium(I) complex to give substituted phenyl(quinolin-8-yl)methanone, phenylquinoxalin-5-ylmethanone, and their derivatives in medium to high yields. The current method offers a highly favorable synthetic pathway to efficiently build related drugs with an 8-benzoylquinoline core structure. This method may prove especially valuable for medicinal chemists for the late-stage introduction of versatile ketone moieties into complex scaffolds for diversity-oriented synthetic strategies." @default.
- W2044128456 created "2016-06-24" @default.
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- W2044128456 date "2013-06-10" @default.
- W2044128456 modified "2023-09-26" @default.
- W2044128456 title "Catalytic Formation of Ketones from Unactivated Esters through Rhodium Chelation-Assisted C–O Bond Activation" @default.
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- W2044128456 doi "https://doi.org/10.1021/jo400949p" @default.
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