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• W2044129020 abstract "A global fit within experimental accuracy of microwave and millimeter-wave transitions in the ground and first excited torsional states of methyl carbamate (H2NC(O)OCH3) is presented. The data set consisting of 995 vt = 0 and 731 vt = 1 transition frequencies combines 1544 new measurements from Kharkov with previously published vt = 0 microwave lines. In this study the so-called “rho axis method” that treats simultaneously both A and E species of the ground and first excited torsional states is applied to the methyl carbamate data set for the first time. The final fit requires only 32 parameters to achieve a unitless weighted standard deviation for the whole fit of 0.89 for a total of 1726 transitions with rotational quantum numbers up to J ⩽ 20 and Ka ⩽ 10. The barrier to internal rotation of the methyl group obtained in this study, V3 = 359.141(24) cm−1, is in good agreement with previously published values but more accurate." @default.
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• W2044129020 date "2006-11-01" @default.
• W2044129020 modified "2023-09-30" @default.
• W2044129020 title "The ground and first excited torsional states of methyl carbamate" @default.
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• W2044129020 doi "https://doi.org/10.1016/j.jms.2006.09.008" @default.
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