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- W2044143492 abstract "A hyperbranched polymer (HPS-DC) synthesized using N,N-diethylamino -dithiocarbamoylstyrene as an inimer and a hyperbranched poly(4-methylstyrene) (HPS-H) prepared by hydrogenation of the HPS-DC are characterized in tetrahydrofuran (THF) solutions by static and dynamic light scattering measurements. The experimental values of z-averaged mean-square radius of gyration ( z1/2) and hydrodynamic radius (RH) of the HPS-H have smaller dimensions than those of the linear polystyrene (PS) at the same degree of polymerization (Nw), whereas the RH of the HPS-DC in the region of Nw z1/2 and RH for the HPS-H are described by a randomly trifunctional branched polymer model with the molecular weight per a branch point (4.55 × 103 g/mol) and the chain dimensions of the linear PS in THF at 25 °C." @default.
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- W2044143492 date "2009-08-01" @default.
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- W2044143492 title "Chain dimension of polystyrene-like hyperbranched polymers with various chain end groups in THF" @default.
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