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- W2044156543 abstract "In Pasadena, (Milliken Lab., USA, 1930) F. Rossetti has observed in Raman spectrum of carbon-dioxide molecule the full symmetric vibration of carbon dioxide appeared as the group of four near lying lines instead of the waited single line. The true interpretation of this enigmatic effect (in that time) was given by E. Fermi -- accidental degeneration of the first excited state of the full symmetric vibration in carbon dioxide. It was the first example of the event observed later in various organic molecules. This event was named as resonance Fermi. The rotational dependence of Fermi type resonance interactions in quasirigid molecules in dominant approximation can be selected in an expansion of the effective vibration-rotation Hamiltonian H<SUB>vib- rot</SUB><SUP>eff</SUP> by the operator H<SUP>(g</SUP>)(Fermi) equals H<SUB>30</SUB> plus (Sigma) <SUB>n</SUB>H<SUB>3n</SUB><SUP>(g</SUP>). Let us consider in detail the problem of the construction of the effective vibration-rotational Hamiltonian H<SUB>VR</SUB> yields H<SUP>eff</SUP> from the point of view of various ordering schemes (grouping) of the vibrational-rotational interactions with sequential analysis of the choice of the convenient grouping adequate to the spectroscopic problem." @default.
- W2044156543 created "2016-06-24" @default.
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- W2044156543 date "1997-03-03" @default.
- W2044156543 modified "2023-09-23" @default.
- W2044156543 title "Rotational dependence of Fermi-type resonance interactions in molecules" @default.
- W2044156543 doi "https://doi.org/10.1117/12.267752" @default.
- W2044156543 hasPublicationYear "1997" @default.
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