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- W2044172557 abstract "Abstract Calculation of the molecular (Van der Waals) component of disjoining pressure of an solution interlayer is rendered difficult by the non-uniformity of the concentration of a dissolved component in this interlayer. This interferes with the direct application of Lifshits et al.'s calculation method. It is the use of an analogue of Gibbs-Duhem' equation that leads to an expression for the disjoining pressure of the interlayer: one component of this expression is equal to the disjoining pressure of a pure solvent, while the other takes into account the influence of the dissolved component. This influence is determined by an excess (quasi-adsorption) of the dissolved component in the interlayer. For determining this excess, the effective Van der Waals' potential energy of the dissolved molecules in the interlayer is used. By introducing a certain simplification, it is possible to obtain a simple analytical expression for the resultant disjoining pressure of the solution interlayer. As the interlayer becomes thinner, the expression changes its sign, whether from the negative to the positive or from the positive to the negative one, or it retains the negative sign. Such a result is indicative of the influence of the effects of osmotic nature, which are similar to those acting in ionic solutions." @default.
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- W2044172557 date "1992-05-01" @default.
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- W2044172557 title "Analytical calculation of repulsion forces arising when the non-ionic diffuse adsorption layers are overlapped" @default.
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- W2044172557 doi "https://doi.org/10.1016/0079-6816(92)90047-l" @default.
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