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- W2044172910 abstract "The historical roots of tandem mass spectrometry or MS/MS (an invaluable tool for determining molecular structure and mixture analysis) are reviewed from the perspective of an active participant. The driving force for creating the first (and only) five-sector tandem mass spectrometer in the period 1962–1965 was to establish mechanisms of low energy ion–molecule reactions unequivocally and to evaluate the dependence of these reactions on ion kinetic energy. The invention and deployment of several other specialized instruments in the 1970s (drift cell and tandem ion cyclotron resonance spectrometers, hybrid tandems, and triple quadrupole instruments) also had fundamental studies of ion reactions as the research objective. The focus on low energy ion chemistry has evolved into collisional activation, the basis of analytical applications of MS/MS, as a natural evolution of scientific interest. The first such studies utilizing a crossed-beam hybrid MS/MS addressed single collision gas phase activation and has recently been extended to surface collision activation. The important parallel development of these methods and the metamorphosis of MS/MS from a suite of research tools into analytical practice using commercial instrumentation are discussed briefly." @default.
- W2044172910 created "2016-06-24" @default.
- W2044172910 creator A5027284991 @default.
- W2044172910 date "2000-12-01" @default.
- W2044172910 modified "2023-10-05" @default.
- W2044172910 title "Development of tandem mass spectrometry: one perspective" @default.
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- W2044172910 doi "https://doi.org/10.1016/s1387-3806(00)00353-5" @default.
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