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- W2044194936 abstract "First examples of heteroleptic arene ruthenium complexes containing dipyrrin ligands with the general formulations [(η6-arene)RuCl(L)] [(arene = C6H6, C10H14; L = 5-(4-cyanophenyl)-dipyrromethene, cydpm; 5-(4-nitrophenyl)-dipyrromethene, ndpm and 5-(4-benzyloxyphenyl)-dipyrromethene, bdpm] have been synthesized. The complexes [(η6-C10H14)RuCl(L)] (L = ndpm and cydpm) reacted with NaN3 and NH4SCN to afford neutral mononuclear complexes [(η6-C10H14)Ru(N3)(L)] and [(η6-C10H14)Ru(SCN)(L)]. Their reactions with EPh3 (E = P, As) and exobidentate ditopic P−P and N−N donor ligands, namely, bis-(diphenylphosphino)methane (dppm) and 4,4′-bipyridine (bpy) in the presence of AgSO3CF3 afforded cationic mono- and binuclear complexes [(η6-C10H14)Ru(L)(EPh3)]SO3CF3, [{(η6-C10H14)Ru(L)}2(μ-dppm)](SO3CF3)2, and [{(η6-C10H14)Ru(L)}2(μ-bpy)](SO3CF3)2, respectively. The reaction products have been characterized by analytical and spectral studies. Molecular structures of the representative complexes [(η6-C10H14)RuCl(cydpm)], [(η6-C6H6)RuCl(cydpm)], [(η6-C10H14)RuCl(ndpm)], [(η6-C10H14)Ru(N3)(ndpm)], and [(η6-C10H14)Ru(PPh3)(ndpm)]SO3CF3 have been determined crystallographically. Redox behavior of the complexes has been investigated by electrochemical studies. Emission spectral studies at room temperature suggested that the complexes under study are non-emissive." @default.
- W2044194936 created "2016-06-24" @default.
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- W2044194936 creator A5048943460 @default.
- W2044194936 creator A5074236241 @default.
- W2044194936 date "2009-07-17" @default.
- W2044194936 modified "2023-09-27" @default.
- W2044194936 title "Heteroleptic Arene Ruthenium Complexes Based on <i>meso-</i>Substituted Dipyrrins: Synthesis, Structure, Reactivity, and Electrochemical Studies" @default.
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- W2044194936 doi "https://doi.org/10.1021/ic9000957" @default.
- W2044194936 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19610658" @default.
- W2044194936 hasPublicationYear "2009" @default.
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