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- W2044202930 endingPage "6798" @default.
- W2044202930 startingPage "6790" @default.
- W2044202930 abstract "Picosecond excited-state singlet–singlet absorption spectra (Sn ← S1) and excited-state decay kinetics are reported for several diazanaphthalenes and a triazanaphthalene in room temperature solution. New Sn (1nπ*) state energies are obtained empirically from these spectra. INDO-PSDCI molecular orbital calculations are used to confirm the Sn ← S1 nature of the excited state transitions observed. Decay rates are calculated from models based on a semiempirical molecular orbital formalism, and these calculated rates are compared with the observed ones. Agreement of the calculated and observed rates are good except in cases of substantial nπ*–ππ* mixing of the actual excited states and in a particular case of high molecular symmetry (1,5-naphthyridine)." @default.
- W2044202930 created "2016-06-24" @default.
- W2044202930 creator A5013187571 @default.
- W2044202930 creator A5028284044 @default.
- W2044202930 date "1986-06-15" @default.
- W2044202930 modified "2023-09-26" @default.
- W2044202930 title "Excited singlet state absorption spectra and relaxation kinetics of the azanaphthalenes" @default.
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- W2044202930 doi "https://doi.org/10.1063/1.450682" @default.
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