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- W2044210663 abstract "A series of Rh2/AlO3 catalysts have been prepared using untreated or pre-sulphated alumina supports. The effect of support sulphation on catalyst activity towards propene and propane combustion has been explored as a function of Rh loading. Light-off temperatures for the total oxidation of both hydrocarbons decrease with increasing Rh content, associated with a transition from small oxidic clusters to large metallic Rh particles. Sulphate promotes both propene and propane combustion equally, with the magnitude of promotion exhibiting only a weak loading dependence. Enhanced catalytic performance is accompanied by Rh reduction and sintering." @default.
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- W2044210663 date "2006-08-01" @default.
- W2044210663 modified "2023-09-25" @default.
- W2044210663 title "Sulphate-promotion and structure-sensitivity in hydrocarbon combustion over Rh/Al2O3 catalysts" @default.
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- W2044210663 doi "https://doi.org/10.1016/j.catcom.2006.01.025" @default.
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