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- W2044218074 abstract "The reduction of chloroacetone over silica-supported noble metal catalysts yielded the hydrodechlorinated (acetone), the hydrogenated (1-chloro-2-propanol), and the hydrodechlorinated–hydrogenated (2-propanol) products at different selectivities depending on the catalyst used. Pd/SiO2 catalyzed the single-step hydrodechlorination preferentially to give acetone selectively. Pt/SiO2 promoted the hydrogenation into 1-chloro-2-propanol concurrently and the consecutive hydrogenation of acetone into 2-propanol as well. Over Rh/SiO2, acetone was transformed to 1-chloro-2-propanol through the addition of hydrogen chloride. The hydrodechlorination activity of noble metals followed the order of Pd > Pt ⪢ Rh > Ru. The high selectivity of Pd/SiO2 toward acetone was not influenced by Pd dispersion. The selectivity of Pt/SiO2 changed largely with Pt dispersion and the hydrogenation of carbonyl group was promoted preferentially over the catalysts with low Pt dispersion." @default.
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- W2044218074 date "2004-09-01" @default.
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- W2044218074 title "Reduction of chloroacetone over silica-supported noble metal catalysts" @default.
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- W2044218074 doi "https://doi.org/10.1016/j.apcata.2004.02.048" @default.
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