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- W2044218384 abstract "Two montmorillonites modified with organic surfactant hexadecyltrimethylammonium bromide via ion exchange were used as adsorbents to remove 2,4,5-trichlorophenol (2,4,5-TCP) from aqueous solution in a batch system. Due to their organophilic nature, exchanged montmorillonites are able to adsorb 2,4,5-TCP at a very high extents. The maximum capacity at 20 °C and pH 4 was 368 and 303 mg/g for organo-montmorillonite (MtC16) and acid-activated-organo-montmorillonite (AMtC16) respectively. Experiments were showed that lower pH increased the amount of adsorbed TCP which reached a maximum at pH 4. The adsorption kinetics was found to follow the pseudo-second-order kinetic model. The non-linear Langmuir model provided the best correlation of experimental data. Isotherms were also used to obtain the thermodynamic parameters. The negative values of ΔG° and ΔH° indicated the spontaneous and exothermal nature of the processes." @default.
- W2044218384 created "2016-06-24" @default.
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- W2044218384 date "2011-05-01" @default.
- W2044218384 modified "2023-09-23" @default.
- W2044218384 title "Adsorption of 2,4,5-trichlorophenol by organo-montmorillonites from aqueous solutions: Kinetics and equilibrium studies" @default.
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- W2044218384 doi "https://doi.org/10.1016/j.cej.2011.03.039" @default.
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