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- W2044222975 abstract "Vapor-phase adsorption of normal hexane onto some common soil constituents and simple mixtures of these constituents at 27°C was studied. Experiments were conducted at zero relative humidity. The constituents can be classified as clays, organic matter and sand. Only the clays were significant adsorbents in both the pure constituent and mixture experiments. In all cases the adsorption isotherms had the Type II sigmoid shape. Adsorbent surface areas were estimated from the two-parameter BET adsorption model. Adsorption capacity, reflected by surface area, of the mixtures could be characterized almost completely by clay content alone. The clays, although possessing much different capacities to adsorb hexane when expressed on a mass basis, exhibited approximately equal adsorption capacities relative to their N2/BET surface areas. Accordingly, the various dry-clay adsorption isotherms when plotted as relative capacity (amount of hexane adsorbed divided by N2/BET surface area) versus normalized concentration were seen to collapse roughly upon one another for a large part of the concentration range. Furthermore, clay BET surface areas estimated from hexane adsorption at 27°C were consistently seen to be approximately 0.73 times that of the value from N2 adsorption." @default.
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- W2044222975 date "1994-06-01" @default.
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- W2044222975 title "Investigation of normal hexane and nitrogen adsorption onto soil constituents and constituent mixtures" @default.
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- W2044222975 doi "https://doi.org/10.1016/0304-3894(93)e0097-l" @default.
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