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• W2044231652 abstract "Abstract In order to prevent the properties, especially transparency, color and health security, of PET/clay nanocomposites from being deteriorated due to the thermal degradation of clay organo‐modifer, we had directly modified sodium montmorillonite (Na + ‐MMT) with PET's monomer, bis (hydroxyethyl) terephthalate (BHET) which had a degradation temperature higher than 400°C, and successfully prepared the hybrids via in situ polymerization. Nanodispersion of clay and the intercalated morphology were determined, and compared with PET/Na + ‐MMT hybirds in which Na + ‐MMT was directly added without any treatment. Improved mechanical properties and T g were observed for the prepared PET/ BHET‐modified clay composites. More importantly, the film produced from the composites had the same transparency as that of pure PET even when 2 wt% of clay was added. Non‐isothermal and isothermal crystallization experiments showed a very good neculation capability of the nano‐dispersed clay, particularly at higher crystallization temperatures. Copyright © 2009 John Wiley & Sons, Ltd." @default.
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• W2044231652 date "2009-02-03" @default.
• W2044231652 modified "2023-10-14" @default.
• W2044231652 title "Preparation and properties of organo-modifier free PET/MMT nanocomposites via monomer intercalation and<i>in situ</i>polymerization" @default.
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• W2044231652 doi "https://doi.org/10.1002/pat.1336" @default.
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