Matches in SemOpenAlex for { <https://semopenalex.org/work/W2044233624> ?p ?o ?g. }
- W2044233624 endingPage "173" @default.
- W2044233624 startingPage "166" @default.
- W2044233624 abstract "Abstract Three new supramolecular networks of cobalt(II), [Co(phen) 2 (SeCN) 2 ] ( 1 ), [Co(bpe) 2 (SeCN) 2 ] n ( 2 ), and {[Co(bps) 2 (SeCN) 2 ]·H 2 O} n ( 3 ) [phen = 1,10-phenanthroline; bpe = 1,2-bis(4-pyridyl)ethane; bps = 4,4-bipyridylsulfide] have been synthesized and characterized by X-ray single crystal structure determination, solid state electronic spectroscopy and thermogravimetric analysis. Complex 1 is a neutral discrete cobalt(II) complex with cis located selenocyanate anions and forms 2D supramolecular layers through π−π interactions. Complexes 2 and 3 have a comparable structure based on metal center bridged by two bpe or bps ligands trough pyridinyl N-donor to give rise to a linear chain. The selenocyanate anions (SeCN − ) bind the metal centers through nitrogen and occupy trans axial positions of the octahedral metal coordination environment. These pendant pseudohalides located on both sides of the 1D polymeric chain help to reinforce the packing through weak interactions. Solid state electronic spectra of all the complexes corroborate the presence of octahedral high spin cobalt(II) centers in all complexes." @default.
- W2044233624 created "2016-06-24" @default.
- W2044233624 creator A5027563927 @default.
- W2044233624 creator A5048450819 @default.
- W2044233624 creator A5074759224 @default.
- W2044233624 date "2014-03-01" @default.
- W2044233624 modified "2023-10-17" @default.
- W2044233624 title "Synthesis, crystal structure, solid state electronic spectra and thermal study of three cobalt(II)–selenocyanate complexes: In situ room temperature transformation of 4,4′-dipyridyldisulfide to 4,4′-dipyridylsulfide" @default.
- W2044233624 cites W1967532943 @default.
- W2044233624 cites W1968627374 @default.
- W2044233624 cites W1974045595 @default.
- W2044233624 cites W1976316797 @default.
- W2044233624 cites W1977469333 @default.
- W2044233624 cites W1987813611 @default.
- W2044233624 cites W1992184988 @default.
- W2044233624 cites W1995341022 @default.
- W2044233624 cites W1999937609 @default.
- W2044233624 cites W2014965018 @default.
- W2044233624 cites W2020708367 @default.
- W2044233624 cites W2028285927 @default.
- W2044233624 cites W2029287154 @default.
- W2044233624 cites W2029455201 @default.
- W2044233624 cites W2039676041 @default.
- W2044233624 cites W2039791068 @default.
- W2044233624 cites W2042031488 @default.
- W2044233624 cites W2048030541 @default.
- W2044233624 cites W2048696022 @default.
- W2044233624 cites W2051167130 @default.
- W2044233624 cites W2052194275 @default.
- W2044233624 cites W2052678132 @default.
- W2044233624 cites W2058679343 @default.
- W2044233624 cites W2063334178 @default.
- W2044233624 cites W2066437651 @default.
- W2044233624 cites W2075021012 @default.
- W2044233624 cites W2076241546 @default.
- W2044233624 cites W2078246215 @default.
- W2044233624 cites W2086730398 @default.
- W2044233624 cites W2090228053 @default.
- W2044233624 cites W2090569714 @default.
- W2044233624 cites W2130302029 @default.
- W2044233624 cites W2130793648 @default.
- W2044233624 cites W2131350133 @default.
- W2044233624 cites W2158744361 @default.
- W2044233624 cites W2163531631 @default.
- W2044233624 cites W2270928042 @default.
- W2044233624 cites W2739977432 @default.
- W2044233624 cites W2891670902 @default.
- W2044233624 doi "https://doi.org/10.1016/j.ica.2014.01.018" @default.
- W2044233624 hasPublicationYear "2014" @default.
- W2044233624 type Work @default.
- W2044233624 sameAs 2044233624 @default.
- W2044233624 citedByCount "10" @default.
- W2044233624 countsByYear W20442336242014 @default.
- W2044233624 countsByYear W20442336242015 @default.
- W2044233624 countsByYear W20442336242019 @default.
- W2044233624 countsByYear W20442336242020 @default.
- W2044233624 countsByYear W20442336242021 @default.
- W2044233624 countsByYear W20442336242023 @default.
- W2044233624 crossrefType "journal-article" @default.
- W2044233624 hasAuthorship W2044233624A5027563927 @default.
- W2044233624 hasAuthorship W2044233624A5048450819 @default.
- W2044233624 hasAuthorship W2044233624A5074759224 @default.
- W2044233624 hasConcept C104317684 @default.
- W2044233624 hasConcept C107814960 @default.
- W2044233624 hasConcept C115624301 @default.
- W2044233624 hasConcept C121332964 @default.
- W2044233624 hasConcept C1276947 @default.
- W2044233624 hasConcept C147789679 @default.
- W2044233624 hasConcept C178790620 @default.
- W2044233624 hasConcept C179104552 @default.
- W2044233624 hasConcept C185592680 @default.
- W2044233624 hasConcept C204241405 @default.
- W2044233624 hasConcept C204530211 @default.
- W2044233624 hasConcept C2777822432 @default.
- W2044233624 hasConcept C4839761 @default.
- W2044233624 hasConcept C515602321 @default.
- W2044233624 hasConcept C55493867 @default.
- W2044233624 hasConcept C8010536 @default.
- W2044233624 hasConcept C97355855 @default.
- W2044233624 hasConceptScore W2044233624C104317684 @default.
- W2044233624 hasConceptScore W2044233624C107814960 @default.
- W2044233624 hasConceptScore W2044233624C115624301 @default.
- W2044233624 hasConceptScore W2044233624C121332964 @default.
- W2044233624 hasConceptScore W2044233624C1276947 @default.
- W2044233624 hasConceptScore W2044233624C147789679 @default.
- W2044233624 hasConceptScore W2044233624C178790620 @default.
- W2044233624 hasConceptScore W2044233624C179104552 @default.
- W2044233624 hasConceptScore W2044233624C185592680 @default.
- W2044233624 hasConceptScore W2044233624C204241405 @default.
- W2044233624 hasConceptScore W2044233624C204530211 @default.
- W2044233624 hasConceptScore W2044233624C2777822432 @default.
- W2044233624 hasConceptScore W2044233624C4839761 @default.
- W2044233624 hasConceptScore W2044233624C515602321 @default.
- W2044233624 hasConceptScore W2044233624C55493867 @default.
- W2044233624 hasConceptScore W2044233624C8010536 @default.
- W2044233624 hasConceptScore W2044233624C97355855 @default.
- W2044233624 hasLocation W20442336241 @default.
- W2044233624 hasOpenAccess W2044233624 @default.