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- W2044238009 abstract "We examined the Donnan distribution of small ions for the NaCl solutions of tetradecyltrimethylammonium chloride (C14TAC) and hexadecyltrimethylammonium chloride (C16TAC) micelles with the nonequilibrium method. The salt concentration of the external solution in equilibrium with the internal solution was determined from the condition of zero emf. In the external solution, the surfactant was added to a range of the critical micelle concentration (cmc). Values of the apparent salt exclusion parameter Γapp did not depend on the external surfactant concentrations me‘ for a narrow range of me‘. The constant Γapp value was taken as the proper salt exclusion parameter value Γ and the minimum value of me‘ giving this constant value was taken as the cmc‘, the cmc of the external solution. We propose, in this way, a procedure to determine experimentally the salt exclusion parameter for the ionic micelle solutions. The Γ values for both C14TAC and C16TAC solutions scarcely depended on the surfactant concentration me, at constant ms except a narrow range (0.5−1) of me/ms in the case of C14TAC. Also, the Γ values for both C14TAC and C16TAC solutions were determined by the ratio me/ms and did not depend on ms. These behaviors differ from those found on linear polyelectrolytes. The Γ values for the C14TAC solutions were greater than those for the C16TAC solutions." @default.
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- W2044238009 date "1999-03-02" @default.
- W2044238009 modified "2023-10-17" @default.
- W2044238009 title "The Donnan Distribution of Salts in the Case of Ionic Micelles" @default.
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- W2044238009 doi "https://doi.org/10.1021/la981021y" @default.
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