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- W2044247292 abstract "The infrared spectra of the NH2 stretching vibrations of aniline+–Arn (n=1–21) cluster cations have been measured by the depletion method. Aniline+–Arn clusters were prepared by near-resonant resonance-enhanced multiphoton ionization (REMPI) of larger aniline–Arm clusters. The red shifts of the NH stretching vibrations were 17–25cm−1, depending on the cluster size. The spectra of small clusters showed that there were hydrogen-bond-type (NH–Ar) and dispersion-type (Ar–π) isomers and that the NH–Ar isomer was more stable. The red shifts of the NH2 stretching vibrations varied with the number of Ar atoms and showed a maximum at n=12 and a local minimum at n≈19." @default.
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- W2044247292 date "2002-03-01" @default.
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- W2044247292 title "Microsolvation of aniline+–Arn (n=1–21) cluster cations investigated by infrared depletion spectroscopy" @default.
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- W2044247292 doi "https://doi.org/10.1016/s0009-2614(02)00194-x" @default.
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