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- W2044247675 abstract "The diastereo- and enantioselective synthesis of (−)-malyngolide [(S, R)-1], an antibiotic against Mycobacterium smegmatis and Streptococcus pyogenes, using the asymmetric Carroll rearrangement as key step is described. Furthermore, the diastereo- and enantioselective synthesis by double α, α′-alkylation using SAMP/RAMP hydrazone methodology affords the diastereomer (+)- epi-malyngolide [(S, S)-1]. The diastereo- and enantioselective synthesis of the anti-biotic (−)-malyngolide via asymmetric dianionic Carroll rearrangement is described. In addition an α, α′-double alkylation pathway using the SAMP/RAMP-hydrazone methodology leading to (+)-epi-malyngolide is carried out.Download : Download full-size image" @default.
- W2044247675 created "2016-06-24" @default.
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- W2044247675 date "1996-04-01" @default.
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- W2044247675 title "Novel asymmetric syntheses of (−)-malyngolide and (+)-epi-malyngolide" @default.
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- W2044247675 doi "https://doi.org/10.1016/0040-4020(96)00236-0" @default.
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