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• W2044257914 endingPage "4607" @default.
• W2044257914 startingPage "4606" @default.
• W2044257914 abstract "An osmium complex bearing a terminal hydrogen-substituted stannylene ligand, Cp*(iPr3P)(H)Os═SnH(trip) (1) (trip = 2,4,6-triisopropylphenyl), has been prepared by stannylene extrusion, and the complex has been structurally characterized. Complex 1 coordinates Lewis bases and activates the O−H bonds of water and methanol. Most interestingly, 1 converts to the metallostannylene complex Cp*(iPr3P)(H)2OsSn(trip) (2) thermally or photochemically by what appears to be a radical process." @default.
• W2044257914 created "2016-06-24" @default.
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• W2044257914 date "2009-03-16" @default.
• W2044257914 modified "2023-09-30" @default.
• W2044257914 title "A Hydrogen-Substituted Osmium Stannylene Complex: Isomerization to a Metallostannylene Complex via an Unusual α-Hydrogen Migration from Tin to Osmium" @default.
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• W2044257914 doi "https://doi.org/10.1021/ja901050m" @default.
• W2044257914 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19290659" @default.
• W2044257914 hasPublicationYear "2009" @default.
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