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• W2044285148 abstract "Magnetoelectric materials have potential for being introduced into next generation technologies, especially memory devices. The AFeO3 (Pna21; A=Al, Ga) system has received attention to better understand the origins of magnetoelectric coupling. The magnetoelectric properties this system exhibits depend on the amount of anti-site disorder present, which is affected by the composition and the method of synthesis. In this study, Al1−xGaxFeO3 was synthesized by the ceramic method and studied by X-ray absorption spectroscopy. Al L2,3-, Ga K-, and Fe K-edge spectra were collected to examine how the average metal coordination number changes with composition. Examination of XANES spectra from Al1−xGaxFeO3 indicate that with increasing Ga content, Al increasingly occupies octahedral sites while Ga displays a preference for occupying the tetrahedral site. The Fe K-edge spectra indicate that more Fe is present in the tetrahedral site in AlFeO3 than in GaFeO3, implying more anti-site disorder is present in AlFeO3." @default.
• W2044285148 created "2016-06-24" @default.
• W2044285148 creator A5001263380 @default.
• W2044285148 creator A5060162570 @default.
• W2044285148 date "2013-01-01" @default.
• W2044285148 modified "2023-09-25" @default.
• W2044285148 title "An X-ray absorption spectroscopic study of the metal site preference in Al1−Ga FeO3" @default.
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• W2044285148 doi "https://doi.org/10.1016/j.jssc.2012.09.015" @default.
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