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- W2044306799 abstract "This paper describes the results of an extensive study oftrans→ cis photoisomerization of various 1,2-diarylethylenes (DAE). The structure effect on the competitive radiative and reactive deactivations and on the isomerization mechanism (singlet/triplet, diabatic/adiabatic) is discussed. The effect of charge-transfer (CT) interactions of DAE with electron donors and acceptors are then presented. Triplet-induced isomerization is generally the common effect in non-polar solvents, and is particularly efficient when a heavy atom is involved. Typical examples of CT-induced triplet photoisomerization of DAE by electron donors and acceptors are llustrated. New results on some fluorescentcis compounds are also reported. Prevalent radical ion formation in polar solvents is shown to generally quench isomerization fromtrans tocis but to induce isomerization fromcis to the more stabletrans radical ion." @default.
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- W2044306799 date "1993-10-01" @default.
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- W2044306799 title "Cis-trans photoisomerization of 1,2-diarylethylenes: Effect of charge transfer interactions" @default.
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- W2044306799 doi "https://doi.org/10.1007/bf03040819" @default.
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