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- W2044310251 abstract "The mechanism and rate of dehydrochlorination of oxide-free PVC films due to Mg Kα X-ray irradiation in vacuum have been studied using X-ray photoelectron spectroscopy. The results show that the photo-dehydrochlorination reaction proceeds according to first-order kinetics and terminates in the formation of conjugate polyene bonds as indicated by change in the film color and chemical shifts in the C 1s spectrum. Chemically shifted C 1s Gaussian components vary in intensity and the chemical shift increases with dose. It has also been shown qualitatively that oxygen functional groups contained in PVC accelerate degradation." @default.
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- W2044310251 date "1982-01-01" @default.
- W2044310251 modified "2023-10-16" @default.
- W2044310251 title "An XPS study of X-ray-induced dehydrochlorination of oxygen-free PVC" @default.
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- W2044310251 doi "https://doi.org/10.1016/0368-2048(82)85028-7" @default.
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