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• W2044332498 abstract "Abstract A new strategy toward the important class of benzomorphans is described. The key bond formation is based on an intramolecular Buchwald–Hartwig enolate arylation reaction. Thus, alkylation of piperidones with ortho ‐bromobenzyl bromides provides the necessary substrates. In the presence of a palladium catalyst, a sterically hindered phosphane ligand, and a base, carbon–carbon bond formation to tricyclic benzomorphan derivatives takes place. After removal of the N ‐protecting group, derivatization reactions are possible. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)" @default.
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• W2044332498 date "2006-12-18" @default.
• W2044332498 modified "2023-09-25" @default.
• W2044332498 title "Synthesis of Benzomorphan Analogues by Intramolecular Buchwald–Hartwig Cyclization" @default.
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• W2044332498 doi "https://doi.org/10.1002/ejoc.200600688" @default.
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