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• W2044333096 abstract "Crystalline-electric-field parameters for the Tm3+ ion in TmAsO4 have been determined. The parameter values give a good fit to the 169Tm quadrupole interaction over the range 1.3-30K and to the Tm3+ electronic level splittings, in contrast to earlier work. Below the distortion temperature (TD=6.13K) a large basal-plane contribution to the electric field gradient arises, due entirely to the cooperative Jahn-Teller effect, whilst the lattice contribution remains small. The origin of the Mossbauer effect lineshape asymmetry in this compound is also discussed." @default.
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• W2044333096 date "1984-03-30" @default.
• W2044333096 modified "2023-10-07" @default.
• W2044333096 title "Crystal-field parameters derived from the quadrupole interaction of169Tm in TmAsO4" @default.
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• W2044333096 doi "https://doi.org/10.1088/0022-3719/17/9/009" @default.
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