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- W2044336415 abstract "The syntheses and structures of the [4 + 1]-coordinated triorganosilane {4-t-Bu-2,6-[P(O)(O-i-Pr)2]2-C6H2}SiPh2H (5) and of the intramolecularly coordinated triorganosiliconium hexafluorophosphate {4-t-Bu-2,6-[P(O)(O-i-Pr)2]2C6H2}SiPh2+PF6- (6) are reported. In the solid state, compound 5 adopts a rotameric form that differs from those found for {4-t-Bu-2,6-[P(O)(OEt)2]2-C6H2}SiPh2R (R = Ph, H)." @default.
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- W2044336415 date "2005-01-22" @default.
- W2044336415 modified "2023-10-13" @default.
- W2044336415 title "Restricted Rotation about the P−C Bond in the Triorganosilane {4-<i>t</i>-Bu-2,6-[P(O)(O-<i>i</i>-Pr)<sub>2</sub>]<sub>2</sub>C<sub>6</sub>H<sub>2</sub>}SiPh<sub>2</sub>H: Identification of a Novel Rotamer and Its Conversion to the Siliconium Salt {4-<i>t-</i>Bu-2,6-[P(O)(O-<i>i</i>-Pr)<sub>2</sub>]<sub>2</sub>C<sub>6</sub>H<sub>2</sub>}SiPh<sub>2</sub><sup>+</sup>PF<sub>6</sub><sup>-</sup>" @default.
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- W2044336415 doi "https://doi.org/10.1021/om0492247" @default.
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