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• W2044340291 abstract "Polycaprolactone (PCL) was covalently grafted on the surface of carbon nanotubes by a simple click reaction of propargyl-terminated PCL (propargyl-PCL) and carbon nanotubes (CNTs) containing azide groups (MWNT-N3). Propargyl-PCL was synthesized by the ring-opening polymerization of ε-caprolactone using propargyl alcohol and stannous octoate. MWNT-N3 was prepared from MWNT having 2-bromoisobutyryl groups (MWNT-Br) with sodium azide by azidation. The melting temperature of propargyl-PCL was shifted to the high temperature in PCL-grafted MWNT. The thermal stability of PCL-grafted MWNT was enhanced as compared to that of propargyl-PCL. PCL was coated on the surface of MWNT with a high density of PCL chains, which showed good solubility of PCL-grafted MWNT in organic solvents. PCL-grafted MWNT was characterized with FT-IR, 1H NMR, Raman, differential scanning calorimetry, thermogravimetric analysis, and scanning electron microscopy." @default.
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• W2044340291 date "2015-01-07" @default.
• W2044340291 modified "2023-10-12" @default.
• W2044340291 title "Synthesis and characterization of polycaprolactone-grafted carbon nanotubes via click reaction" @default.
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• W2044340291 doi "https://doi.org/10.1080/15685543.2015.999300" @default.
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